X射线荧光光谱法分析不同类型岩石中10种主量元素的测试能力验证   总被引：4，自引：3，他引：1  

王建其  柳小明 《岩矿测试》2016,35(2):145-151

以28个不同类型岩石标样作外标,用玻璃熔片法制样,采用经验系数法进行基体校正,建立了X射线荧光光谱法(XRF)测定不同类型岩石中硅铝钙镁等10种主量元素的分析方法。该方法被用于参与GeoPT分析测试能力验证,15年来分析了23个不同类型的岩石验证样品。经验证该方法对SiO_2、Al_2O_3、K_2O和CaO具有非常好的分析效果(所有测定结果的|Z|2);对于MgO、MnO、TiO_2和Na_2O四个元素,尽管各有一个样品的分析结果的|Z|2,这主要是样品与标样的基体差异较大造成了低含量样品测定结果超差,但依然可获得好的分析效果;当TFe_2O_31.0%,P_2O_5含量在0.08%~0.80%区间时,分析结果的|Z|2,满足分析期望。总体上所建立的XRF分析方法稳定,可满足应用地球化学实验室测试不同类型岩石中10种主量元素的分析期望。  相似文献   

同化FY3B/IRAS资料对GRAPES分析场影响诊断     

王根  刘文静  唐怀瓯 《气象与环境科学》2016,39(3):15-21

GRAPES(Globe and Regional Assimilation and Prediction System)变分系统能够同化常规资料和非常规卫星资料,这些被同化的资料究竟对同化系统得到的分析场有何影响,目前国内外尚未见相关的研究文献。为此,首次采用基于信息熵信号自由度思想,诊断风云三号B星(FY3B)红外分光计(Infrared Atmospheric Sounder,IRAS)资料对GRAPES分析场的影响。诊断过程中,采用数值逼近方法,统计2012年12月24日18时到2013年1月22日00时共114个时次IRAS资料对GRAPES分析场影响,结果表明,IRAS中高层通道亮温资料对GRAPES分析场影响比地表通道20观测亮温的影响大,地表通道8和9观测亮温对分析场影响较大。前24个GRAPES变分同化时次每个时次IRAS通道亮温对分析场影响的贡献率分析结果显示,高层通道和H_2O通道贡献率较大。个例分析结果表明,在同化探空资料基础上加入IRAS资料后,温度和湿度增量场变化幅度较大,表明IRAS资料对分析场有降温和增湿作用。  相似文献   

Determination of the factors governing soil erodibility using hyperspectral visible and near-infrared reflectance spectroscopy     

《International Journal of Applied Earth Observation and Geoinformation》2016

Soil erodibility, which is difficult to estimate and upscaling, was determined in this study using multiple spectral models of soil properties (soil organic matter (SOM), water-stable aggregates (WSA) > 0.25 mm, the geometric mean radius (D_g)). Herein, the soil erodibility indicators were calculated, and soil properties were quantitatively analyzed based on laboratory simulation experiments involving two selected contrasting soils. In addition, continuous wavelet transformation was applied to the reflectance spectra (350–2500 nm) of 65 soil samples from the study area. To build the relationship, the soil properties that control erodibility were identified prior to the spectral analysis. In this study, the SOM, D_g and WSA >0.25 mm were selected to represent the most significant soil properties controlling erodibility and describe the erodibility indicator based on a logarithmic regression model as a function of SOM or WSA > 0.25 mm. Five, six and three wavelet features were observed to calibrate the estimated soil properties model, and the best performance was obtained with a combination feature regression model for SOM (R² = 0.86, p < 0.01), D_g (R² = 0.79, p < 0.01) and WSA >0.25 mm (R² = 0.61, p < 0.01), respectively. One part of the wavelet features captured amplitude variations in the broad shape of the reflectance spectra, and another part captured variations in the shape and depth of the soil dry substances. The wavelet features for the validated dataset used to predict the SOM, WSA >0.25 mm and D_g were not significantly different compared with the calibrated dataset. The synthesized spectral models of soil properties, and the formation of a new equation for soil erodibility transformed from the spectral models of soil properties are presented in this study. These results show that a spectral analytical approach can be applied to complex datasets and provide new insights into emerging dynamic variation with erodibility estimation.  相似文献   

粉色水晶内针状包裹体的成分与分布特征研究   总被引：1，自引：1，他引：0  

胡哲  郭颖 《岩矿测试》2018,37(3):306-312

粉色水晶内部的针状包裹体常被认为是三组呈三方对称的金红石或蓝线石,至今未有定论。本文选取含有针状包裹体的4颗星光粉晶,利用宝石学显微镜、激光拉曼光谱仪及紫外可见分光光度计对样品进行观察与测试,以确定包裹体的分布特征及矿物种类。无损拉曼测试发现包裹体的特征振动峰949 cm-1、999 cm-1与蓝线石标准峰相匹配,可确定针状包裹体为蓝线石或与其极为相近的矿物。放大检查发现,包裹体直径约0.5μm,长度可达毫米级,近定向分布,整体上呈汇聚状,在某些位置可粗略分为三组,同组针状包裹体近似平行分布。造成六射星光的三组蓝线石立体相交,未观察到明显的三方对称关系,与水晶的结晶习性无直接关系,故认为蓝线石为先成包裹体,在水晶的生长过程中被捕获。紫外可见分光光谱仅显示粉色蓝线石的特征吸收,表明大量的粉色蓝线石包裹体对粉色水晶的粉色有一定贡献。  相似文献   

大气红外窗区(10.5-11.5μm和11.5-12.5μm)辐射传输的敏感性试验   总被引：1，自引：0，他引：1  

魏丽  钟强 《高原气象》1988,(3)

大气窗区卫星红外遥感的辐射资料可应用于地表温度的确定,但必须考虑大气影响。为此,本文利用辐射传输模式和中纬度及青藏高原模式大气,用数值模拟的方法研究了大气和地表状态(大气温、湿廓线、地表温度与高度)的改变对大气顶红外窗区射出辐射的影响以及射出辐射对发射方向(天顶角)依赖关系。主要结论见正文小结。  相似文献   

苏皖凹凸棒石矿物红外光谱特征研究   总被引：13，自引：0，他引：13  

郑自立  田煦 《岩石学报》1990,6(2)

苏皖凹凸捧石粘土矿物包括沉积、风化及火山碎屑蚀变三种成因类型。成矿物质来源于内陆浅水湖盆水下玄武岩风化蚀变及地表玄武岩的风化。不同成因类型的凹凸棒石在矿物晶体结晶程度上有较大差异。通常,由风化作用生成并与碳酸盐共生的沉积型凹凸棒石结晶程度低,较纯的并与硅质岩共生的沉积型凹凸棒石结晶程度高。它们在红外吸收光谱特征上表现为:前者红外振动吸收带分裂程度低,吸收峰弱且峰形钝。后者红外振动吸收带分裂程度高,吸收峰尖锐。因此研究凹凸捧石的红外吸收光谱特征可基本上区分出它们的成因类型。本文还对凹凸棒石红外吸收光谱振动波数带进行了划分,并对相应的振动类型作了探讨。  相似文献   

Theory and Experimental Results about the Application of Remote Sensing to Earthquake Prediction     

Deng Mingde  Cui Chengyu  Geng NaiguangComprehensive Observation Brigade  SSB  Beijing  ChinaInstitute of Remote Sensing Application  Academia Sinica  Beijing  ChinaInstitute of Geophysics  SSB  Beijing  China 《中国地震研究》1995,(2)

In this paper,the theory for applying remote sensing to earthquake prediction has been elucidated and an experiment has been made.Through the experiment,it has been found that the characteristics and temperature of infrared radiant of rocks vary as a function of rock stress,the order of magnitude of radiance variation is 10-5(W/cm2 sr um),the amount of variation of the radiant temperature is 0.2℃~0.8℃ and some significant precursor information has been discovered.The experiment has verified preliminarily that the advanced technology of remote sensing can be applied to earthquake prediction.  相似文献   

大气中微量气体的红外吸收          下载免费PDF全文

王松皋  张广顺 《应用气象学报》1995,6(1):70-75

文章介绍了测定大气中微量气体CO2与CH4透过率的试验。所用的主要设备是FTIR分光计及可变光程吸收池。文中叙述了主要实验结果与数据处理方法，同时用FASCODE-2程序计算了对应实验条件下CO2与CH4的透过率，并与实验结果作了比较。  相似文献   

应用ATOVS资料反演大气温湿廓线   总被引：3，自引：2，他引：3  

王寅虎  孙龙祥 《气象科学》2001,21(3):348-354

本文用牛顿迭代的方法反演NOAA-15极轨气象卫星ATOVS资料，求解大气温度廓线和水汽廓线，本文利用一阶变分原理从辐射传输方程中得到了大气温度、水汽权重函数的解析形式，并改进了传统使用的线性迭代方法，利用牛顿非线性迭代方法求解大气表层温度，大气温度廓线及大气水汽廓线，并根据大气参量的自相关性，将大气温度廓线、大气水汽廓线用经验正交函数（EOF）的线性组合表示，减少了要反演的参数，提高了反演稳定性和迭代速度。  相似文献   

An Approach for Classification of Groundwaters by Synchronous Fluorescence Spectroscopy and Discriminant Analysis     

W. Geyer  L. Brüggemann  U. Schmitz 《洁净——土壤、空气、水》1996,24(5):206-211

Monitoring and evaluation of groundwater quality in drinking water protectorates is of particular interest if the uncontrolled entry of pollutants, for example by infiltrating river water, cannot be excluded. A fluorescence spectroscopic method is presented as possible alternative to the conventional expensive hydrochemical investigations. This method uses the information yielded by synchronous fluorescence spectra. After a Fourier transformation of the original spectra and a following discriminant analysis, the samples can be classified in different groups corresponding to the different types of groundwater. The method was tested in the drinking water protectorate of a waterworks of a German metropolis (Halle, Sachsen-Anhalt). We found a prediction rate of about 90% in the investigated case.  相似文献